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Chemistry Question 67 – NEET-UG 2024

Match List I with List II. List I (Molecule)List II (Number and types of bond/s between two carbon atoms)A. ethaneI. one σ-bond and two π-bondsB. etheneII. two π-bondsC. carbon molecule, C2III. one σ-bondD. ethyneIV. one σ-bond and one π-bond Choose the correct answer from the options given below:

Covalent bonds can be single, double, or triple, each composed of a specific combination of sigma (σ) and pi (π) bonds.

Step 1: Analyze Bonding in Each Molecule✦ Active

Let's determine the number of σ and π bonds between the two carbon atoms for each molecule in List I:

A. Ethane (C2H6): Has a C-C single bond. A single bond consists of one σ-bond. (Matches List II - III)

B. Ethene (C2H4): Has a C=C double bond. A double bond consists of one σ-bond and one π-bond. (Matches List II - IV)

C. Carbon molecule (C2): According to molecular orbital theory, the C2 molecule has a bond order of 2, consisting of two π-bonds and no σ-bond in its ground state. (Matches List II - II)

D. Ethyne (C2H2): Has a CC triple bond. A triple bond consists of one σ-bond and two π-bonds. (Matches List II - I)

💡 Teacher's Secret Hint

Remember the general rule: single bond = 1σ, double bond = 1σ+1π, triple bond = 1σ+2π. The C2 molecule is an exception to this simple rule for diatomic molecules.

Step 2: Match List I with List II○ Expand

Based on the analysis:

A. Ethane III (one σ-bond)

B. Ethene IV (one σ-bond and one π-bond)

C. Carbon molecule, C2 II (two π-bonds)

D. Ethyne I (one σ-bond and two π-bonds)

Step 3: Select the Correct Option○ Expand

The correct matching sequence is A-III, B-IV, C-II, D-I. Comparing this with the given options, option (2) matches this sequence.

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