StemCET Logo

Chemistry Question 135 – AP-EAMCET 2026

Observe the following statements about the oxides of group 14 elements I. CO2 is an acidic oxide but CO is a neutral oxide II. Cristobalite is the crystalline form of silica III. Liquid CO is called dry ice IV. Both CO and CO2 act as Lewis acids The correct statements are

Recall the general classification of oxides (acidic, basic, neutral, amphoteric) based on the nature of the element and their reactions with acids and bases.

Step 1: Evaluate Statement I: Acidic/Neutral Nature of Carbon Oxides✦ Active

Statement I claims that CO2 is an acidic oxide and CO is a neutral oxide. Carbon dioxide (CO2) reacts with water to form carbonic acid (H2CO3), and it reacts with bases, confirming its acidic nature. Carbon monoxide (CO) is known to be a neutral oxide, meaning it does not react with acids or bases. Therefore, Statement I is correct.

💡 Teacher's Secret Hint

Acidic oxides are typically formed by non-metals and react with bases or water to form acids. Neutral oxides do not react with acids or bases.

Step 2: Evaluate Statement II: Crystalline Form of Silica○ Expand

Statement II states that Cristobalite is a crystalline form of silica. Silica (SiO2) exists in several crystalline forms (polymorphs), including quartz, tridymite, and cristobalite. Cristobalite is indeed one of the high-temperature forms of silica. Therefore, Statement II is correct.

💡 Teacher's Secret Hint

Remember that many compounds can exist in different structural forms, known as allotropes or polymorphs, each with distinct properties.

Step 3: Evaluate Statement III: Definition of Dry Ice○ Expand

Statement III claims that liquid CO is called dry ice. Dry ice is the common name for solid carbon dioxide (CO2), which sublimes directly from solid to gas at room temperature and pressure. Liquid carbon monoxide (CO) is just liquid CO, not dry ice. Therefore, Statement III is incorrect.

💡 Teacher's Secret Hint

Confusion between CO and CO2 is common. Always double-check the chemical formula for common substances.

Step 4: Evaluate Statement IV: Lewis Acid Behavior of Carbon Oxides○ Expand

Statement IV asserts that both CO and CO2 act as Lewis acids. A Lewis acid is an electron-pair acceptor. In CO2, the central carbon atom is electron-deficient and can accept electron pairs, for example, from hydroxide ions (OH), thus acting as a Lewis acid. Carbon monoxide (CO), however, typically acts as a Lewis base (electron-pair donor) through the lone pair on its carbon atom, especially in coordination chemistry to form metal carbonyls. While it can accept electron density into its antibonding orbitals (acting as a π-acceptor ligand), it is not generally classified as a Lewis acid in the typical sense of forming a bond by accepting a lone pair from a Lewis base. Therefore, the statement that *both* act as Lewis acids is incorrect because CO is primarily a Lewis base. Statement IV is incorrect.

💡 Teacher's Secret Hint

Recall that a Lewis acid accepts an electron pair to form a new bond, while a Lewis base donates an electron pair. Carbon monoxide is a classic example of a neutral Lewis base ligand.

Step 5: Conclusion○ Expand

Based on the evaluation: Statement I: Correct Statement II: Correct Statement III: Incorrect Statement IV: Incorrect The correct statements are I and II only. This corresponds to option 1.

💡 Teacher's Secret Hint

Always review all options and statements thoroughly before making a final selection.

✦ STEM Console utilizes AI models to generate step-by-step explanations and math clues. AI can make mistakes.