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Physics Question 97 – AP-EAMCET 2025

When a polyatomic gas is heated at constant pressure, the percentage of heat given to the gas that is converted into external work is (Ratio of the specific heat capacities of the gas = 43)

Understand the definitions of heat supplied at constant pressure (Qp) and work done (W) by a gas in an isobaric process.

Step 1: Identify Given Information and Goal✦ Active

The problem states that a polyatomic gas is heated at constant pressure (isobaric process). We are given the ratio of specific heat capacities, γ=CpCv=43. We need to find the percentage of heat given to the gas that is converted into external work, which is WQp×100%, where W is the work done and Qp is the heat supplied at constant pressure.

💡 Teacher's Secret Hint

Remember that for an isobaric process, the pressure remains constant, which simplifies the calculation of work done.

Step 2: Express Work Done and Heat Supplied in Terms of Specific Heats○ Expand

For an isobaric process, the heat supplied to n moles of gas for a temperature change ΔT is given by:

Qp=nCpΔT

The work done by the gas in an isobaric process is W=PΔV. Using the ideal gas law PV=nRT, we have PΔV=nRΔT. So, the work done is:

W=nRΔT
💡 Teacher's Secret Hint

Ensure you use molar specific heats (Cp, Cv) and the universal gas constant (R) when dealing with n moles of gas.

Step 3: Calculate the Ratio of Work Done to Heat Supplied○ Expand

Now, we can find the ratio WQp:

WQp=nRΔTnCpΔT=RCp

We know Mayer's relation: CpCv=R. Substituting R into the ratio:

WQp=CpCvCp=1CvCp

We are given γ=CpCv. Therefore, CvCp=1γ. Substituting this into the expression:

WQp=11γ
💡 Teacher's Secret Hint

This derived formula, WQp=11γ, is a useful shortcut for isobaric processes.

Step 4: Substitute the Given Value of γ and Calculate the Percentage○ Expand

Given γ=43. Substitute this value into the ratio:

WQp=114/3=134=14

To express this as a percentage, multiply by 100%:

Percentage=14×100%=25%
💡 Teacher's Secret Hint

Always double-check the units and ensure the final answer is in the requested format (percentage in this case).

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