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Chemistry Question 74 – JEE-MAIN 2025

An organic compound weighing 500 mg, produced 220 mg of CO2, on complete combustion. The percentage composition of carbon in the compound is _______ \%. (nearest integer) (Given molar mass in g mol1 of C:12,O:16)

In combustion analysis, all the carbon from the organic compound is converted into carbon dioxide.

Step 1: Calculate Molar Mass of CO2✦ Active

The molar mass of carbon (C) is 12 g mol1 and oxygen (O) is 16 g mol1. The molar mass of carbon dioxide (CO2) is calculated as:

Molar mass of CO2=12+(2×16)=12+32=44 g mol1
Step 2: Determine Mass of Carbon in CO2○ Expand

From the molar mass, 44 g of CO2 contains 12 g of carbon. We produced 220 mg of CO2. The mass of carbon in this CO2 is:

Mass of C=(Atomic mass of CMolar mass of CO2)×Mass of CO2 Mass of C=(1244)×220 mg=60 mg
💡 Teacher's Secret Hint

Ensure units are consistent (mg in this case) throughout the calculation.

Step 3: Calculate Percentage Composition of Carbon○ Expand

The 60 mg of carbon came from the 500 mg organic compound. The percentage composition of carbon in the compound is:

Percentage of C=(Mass of CMass of organic compound)×100% Percentage of C=(60 mg500 mg)×100%=605%=12%

The percentage composition of carbon in the compound is 12%. Rounded to the nearest integer, it is 12.

💡 Teacher's Secret Hint

Remember to express the final answer as a percentage and round to the nearest integer as requested.

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