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Chemistry Question 62 – JEE-MAIN 2026

Consider |x| is the difference in oxidation states of Mn in highest manganese fluoride and highest manganese oxide. The ions with |x| number of unpaired electrons from the following are: A. Sc3+ B. Zn2+ C. V2+ D. Fe2+ E. Co2+

Identify the highest stable oxidation state of Manganese in its fluoride and oxide compounds.

Step 1: Determine the value of |x|✦ Active

The highest oxidation state of Manganese (Mn) in an oxide is +7, found in Mn2O7. The highest stable oxidation state of Mn in a fluoride is +4, found in MnF4. The difference in these oxidation states is |x|=|74|=3.

Step 2: Determine unpaired electrons for each ion○ Expand

We need to find ions with 3 unpaired electrons. Let's determine the electron configuration and number of unpaired electrons for each given ion:

Sc3+:[Ar]0 unpaired electrons Zn2+:[Ar]3d100 unpaired electrons V2+:[Ar]3d33 unpaired electrons Fe2+:[Ar]3d64 unpaired electrons Co2+:[Ar]3d73 unpaired electrons
💡 Teacher's Secret Hint

Remember to remove electrons from the outermost s-orbital first when forming cations of transition metals.

Step 3: Identify ions with |x| unpaired electrons○ Expand

Based on the calculations, the ions with 3 unpaired electrons (which is |x|) are V2+ and Co2+. This corresponds to options C and E.

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