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Chemistry Question 51 – JEE-MAIN 2026

The ratio of mass percentage (w/w) of C : H in a hydrocarbon is 12 : 1. It has two carbon atoms. The weight (in g) of CO2(g) formed when 3.38 g of this hydrocarbon is completely burnt in oxygen is : (Given : Molar mass in g mol1 C : 12, H : 1, O : 16)

Use the given mass ratio of carbon to hydrogen and the number of carbon atoms to find the exact chemical formula of the hydrocarbon.

Step 1: Determine the Molecular Formula of the Hydrocarbon✦ Active

The mass ratio of C:H is 12:1. Given molar mass of C is 12 g/mol and H is 1 g/mol. The mole ratio of C:H is 1212:11=1:1. Thus, the empirical formula is CH. Since the hydrocarbon has two carbon atoms, its molecular formula must be (CH)2=C2H2. The molar mass of C2H2 is (2×12)+(2×1)=26 g/mol.

Step 2: Write and Balance the Combustion Reaction○ Expand

The complete combustion reaction for C2H2 is:

2C2H2(g)+5O2(g)4CO2(g)+2H2O(l)

From the balanced equation, 2 moles of C2H2 produce 4 moles of CO2, which simplifies to 1 mole of C2H2 producing 2 moles of CO2.

Step 3: Calculate the Mass of CO2 Formed○ Expand

First, calculate the moles of C2H2 burnt:

Moles of C2H2=massmolar mass=3.38 g26 g/mol=0.13 mol

Using the stoichiometric ratio from Step 2, calculate the moles of CO2 produced:

Moles of CO2=0.13 mol C2H2×2 mol CO21 mol C2H2=0.26 mol CO2

Finally, calculate the mass of CO2 formed. The molar mass of CO2=12+(2×16)=44 g/mol.

Mass of CO2=0.26 mol×44 g/mol=11.44 g
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