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Chemistry Question 62 – JEE-MAIN 2025

On combustion 0.210 g of an organic compound containing C, H and O gave 0.127 g H2O and 0.307 g CO2. The percentages of hydrogen and oxygen in the given organic compound respectively are:

In combustion analysis, all carbon in the organic compound is converted to CO2 and all hydrogen to H2O. Oxygen is determined by difference.

Step 1: Calculate masses of C and H✦ Active

First, determine the mass of carbon and hydrogen present in the organic compound from the masses of CO2 and H2O produced, respectively. Use the standard atomic masses (C=12,H=1,O=16). Molar mass of CO2=44 g/mol, Molar mass of H2O=18 g/mol.

Mass of C=0.307 g CO2×12 g C44 g CO2=0.083727 g Mass of H=0.127 g H2O×2 g H18 g H2O=0.014111 g
Step 2: Calculate mass and percentage of O○ Expand

Next, calculate the mass of oxygen in the organic compound by subtracting the masses of carbon and hydrogen from the total mass of the compound. Then, determine the percentage of oxygen.

Mass of O=Mass of compoundMass of CMass of H Mass of O=0.210 g0.083727 g0.014111 g=0.112162 g % O=0.112162 g0.210 g×100=53.41%
Step 3: Calculate percentage of H and identify the option○ Expand

Finally, calculate the percentage of hydrogen in the organic compound and compare with the given options.

% H=0.014111 g0.210 g×100=6.72% The percentages of hydrogen and oxygen are approximately 6.72% and 53.41% respectively, which corresponds to option 4.
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