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Chemistry Question 52 – JEE-MAIN 2026

The Bohr radius of a hydrogen like species is 70.53 pm. The species and the stationary state (n) are respectively (Given : Hydrogen atom Bohr radius is 52.9 pm)

Recall the Bohr model for hydrogen-like species and how the radius of an orbit depends on the principal quantum number and atomic number.

Step 1: Identify the relevant formula✦ Active

The Bohr radius for a hydrogen-like species is given by the formula:

rn=r0n2Z

Where rn is the radius of the n-th orbit, r0 is the Bohr radius of hydrogen (52.9 pm), n is the principal quantum number, and Z is the atomic number.

Step 2: Substitute values from options and calculate rn○ Expand

We will test each option by substituting the atomic number (Z) and principal quantum number (n) into the formula:

1. For Li2+ (Z=3), n=3: r3=52.9 pm×323=52.9 pm×3=158.7 pm

2. For He+ (Z=2), n=3: r3=52.9 pm×322=52.9 pm×4.5=238.05 pm

3. For He+ (Z=2), n=2: r2=52.9 pm×222=52.9 pm×2=105.8 pm

4. For Li2+ (Z=3), n=2: r2=52.9 pm×223=52.9 pm×4370.53 pm

💡 Teacher's Secret Hint

Remember that Z is the atomic number, which is 3 for Lithium and 2 for Helium.

Step 3: Compare calculated radius with given value○ Expand

The calculated radius for Li2+ in the n=2 state (70.53 pm) matches the given Bohr radius of the hydrogen-like species (70.53 pm). Therefore, option 4 is the correct answer.

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