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Chemistry Question 57 – NEET-UG 2023

Which one is an example of heterogeneous catalysis?

Recall the definition of heterogeneous catalysis, where the catalyst and reactants are in different physical phases.

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Ninja StrategyPhase Mismatch Identification

Quickly identify the physical states of reactants and catalysts for each option. Heterogeneous catalysis requires different phases.

Step 1: Define Heterogeneous Catalysis✦ Active

Heterogeneous catalysis occurs when the catalyst and the reactants are in different physical phases. For example, gaseous reactants reacting on a solid catalyst surface.

💡 Teacher's Secret Hint

Distinguish this from homogeneous catalysis where all components are in the same phase.

Step 2: Analyze Each Option for Phases○ Expand

Option (1): Oxidation of SO2(g) to SO3(g) using oxides of nitrogen (NOx(g)) as catalyst. All are gases, so it's homogeneous catalysis. Option (2): Hydrolysis of sugar (aqueous) catalysed by H+(aq) ions. All are in the aqueous/liquid phase, so it's homogeneous catalysis. Option (3): Decomposition of O3(g) in presence of NO(g). Both are gases, so it's homogeneous catalysis. Option (4): Combination of N2(g) and H2(g) to form NH3(g) in the presence of finely divided iron (Fe(s)). Reactants are gases, catalyst is solid.

Step 3: Conclude the Type of Catalysis○ Expand

Since the reactants (N2(g), H2(g)) are in the gaseous phase and the catalyst (Fe(s)) is in the solid phase, option (4) represents heterogeneous catalysis.

💡 Teacher's Secret Hint

The Haber-Bosch process is a classic industrial example of heterogeneous catalysis.

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