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Physics Question 32 – JEE-MAIN 2026

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Statement I: Change in internal energy of a system containing n mole of ideal gas can be written as ΔU=nCV(TfTi)=nRγ1(TfTi), where γ=CpCv, Ti = initial temperature, Tf = final temperature. Statement II: Relation between degree of freedom f and γ(=Cp/CV) is γ=1+2f Choose the correct answer from the options given below

Recall the fundamental formula for the change in internal energy of an ideal gas and the definitions of specific heats.

Step 1: Evaluate Statement I (Assertion A)✦ Active

Statement I gives the change in internal energy of an ideal gas as ΔU=nCV(TfTi)=nRγ1(TfTi). The first part, ΔU=nCV(TfTi), is the fundamental definition for an ideal gas. To verify the second part, we use Mayer's relation CpCV=R and the definition γ=CpCV. From these, we get Cp=γCV. Substituting into Mayer's relation: γCVCV=RCV(γ1)=RCV=Rγ1. Substituting this into the internal energy formula yields ΔU=n(Rγ1)(TfTi). Thus, Statement I is True.

Step 2: Evaluate Statement II (Reason R)○ Expand

Statement II provides the relation between the degree of freedom f and γ as γ=1+2f. For an ideal gas, the molar specific heat at constant volume is CV=f2R. Using Mayer's relation, Cp=CV+R=f2R+R=R(f2+1)=R(f+22). The adiabatic index γ=CpCV=R(f+22)R(f2)=f+2f=1+2f. Thus, Statement II is True.

Step 3: Determine if R is the correct explanation for A○ Expand

Both Statement I (Assertion A) and Statement II (Reason R) are true. Statement I's second form for ΔU is derived from the definition of γ and Mayer's relation (CV=Rγ1). Statement II gives a fundamental relation between γ and the degrees of freedom f. While related to ideal gas properties, Statement II does not directly explain the derivation of the internal energy formula in terms of γ as presented in Statement I. Therefore, R is not the correct explanation for A.

💡 Teacher's Secret Hint

Distinguish between a true statement and a correct explanation. A correct explanation should logically justify the assertion.

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