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Physics Question 34 – JEE-MAIN 2026

A mixture of carbon dioxide and oxygen has volume 8310 cm3, temperature 300 K, pressure 100 kPa and mass 13.2 g. The number of moles of carbon dioxide and oxygen gases in the mixture respectively are _______. (Assume both carbon dioxide and oxygen gases behave like ideal gases) [R=8.31 J/molK]

For an ideal gas mixture, the total number of moles can be determined using the ideal gas law with the total pressure, volume, and temperature. The total mass of the mixture is the sum of the masses of individual components.

Step 1: Calculate Total Moles✦ Active

Use the Ideal Gas Law, PV=ntotalRT, to find the total moles of the gas mixture. Convert units to SI: V=8310 cm3=8.31×103 m3, P=100 kPa=105 Pa.

ntotal=PVRT=(105 Pa)(8.31×103 m3)(8.31 J/molK)(300 K)=100300=13 mol
Step 2: Set up Mass Balance Equation○ Expand

Let nCO2 be the moles of carbon dioxide and nO2 be the moles of oxygen. The molar mass of CO2 is 44 g/mol and O2 is 32 g/mol. The total mass is 13.2 g. This gives us a system of two linear equations:

nCO2+nO2=13(Equation 1) 44nCO2+32nO2=13.2(Equation 2)
Step 3: Solve the System of Equations○ Expand

From Equation 1, nO2=13nCO2. Substitute this into Equation 2:

44nCO2+32(13nCO2)=13.2 44nCO2+32332nCO2=13.2 12nCO2=13.2323=39.6323=7.63 nCO2=7.6360.211 mol

Then, calculate nO2:

nO2=13nCO2=130.211=0.3330.211=0.122 mol

Rounding to two decimal places, nCO2=0.21 mol and nO2=0.12 mol. This matches option 3.

💡 Teacher's Secret Hint

Ensure consistent units throughout the calculation, especially when using the ideal gas law.

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