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Chemistry Question 60 – NEET-UG 2026

2AkB is a zero-order reaction, where k=1.0 mol L1 min1. If the initial concentration of A is 2 M, then the time taken to complete 75% of the reaction will be

Understand the integrated rate law for a zero-order reaction.

Step 1: Identify the Reaction Order and Rate Law✦ Active

The problem states that the reaction is a zero-order reaction. The integrated rate law for a zero-order reaction is given by the equation:

[A]t=[A]0kt

This can be rearranged to solve for time t:

t=[A]0[A]tk
Step 2: Calculate the Concentration of Reactant Remaining○ Expand

The initial concentration of A is given as [A]0=2 M. The reaction is 75% complete, which means 75% of the initial reactant has been consumed. Therefore, 25% of the reactant remains.

[A]t=(10.75)×[A]0=0.25×2 M=0.5 M
💡 Teacher's Secret Hint

Ensure to calculate the remaining concentration, not the consumed amount, for the [A]t term in the rate law.

Step 3: Calculate the Time Taken○ Expand

Substitute the initial concentration, remaining concentration, and the rate constant into the rearranged integrated rate law:

t=[A]0[A]tk=2 M0.5 M1.0 mol L1 min1

Since 1 M=1 mol L1:

t=1.5 M1.0 M min1=1.5 min
💡 Teacher's Secret Hint

Always check that the units cancel out correctly to give the desired unit for time.

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