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Chemistry Question 51 – JEE-MAIN 2026

Match List - I with List - II. List - IList - IIMass of substanceNumber of atomsA. 1.8 mg waterI. 2×10−4×NAB. 9.8 mg sulphuric acidII. 1.5×10−4×NAC. 1.8 mg carbonIII. 3×10−4×NAD. 5.85 mg salt (NaCl)IV. 7×10−4×NA Choose the correct answer from the options given below :

To find the number of atoms, you need to first calculate the number of moles of the substance and then multiply by Avogadro's number and the number of atoms per molecule/formula unit.

Step 1: Calculate Moles and Atoms per Molecule for each substance✦ Active

First, convert the given mass from mg to g and calculate the number of moles for each substance using their respective molar masses. Then, identify the number of atoms present in one molecule or formula unit of each substance.

A. Water (H2O):Molar mass=18 g/molMoles=1.8×10−3 g18 g/mol=1×10−4 molAtoms per molecule=3 (2H + 1O)B. Sulphuric acid (H2SO4):Molar mass=98 g/molMoles=9.8×10−3 g98 g/mol=1×10−4 molAtoms per molecule=7 (2H + 1S + 4O)C. Carbon (C):Molar mass=12 g/molMoles=1.8×10−3 g12 g/mol=1.5×10−4 molAtoms per molecule=1 (monatomic)D. Salt (NaCl):Molar mass=58.5 g/molMoles=5.85×10−3 g58.5 g/mol=1×10−4 molAtoms per formula unit=2 (1Na + 1Cl)
Step 2: Calculate Total Number of Atoms for each substance○ Expand

Multiply the moles by Avogadro's number (NA) and the number of atoms per molecule/formula unit to find the total number of atoms.

A. Water: (1×10−4)×NA×3=3×10−4NAB. Sulphuric acid: (1×10−4)×NA×7=7×10−4NAC. Carbon: (1.5×10−4)×NA×1=1.5×10−4NAD. Salt (NaCl): (1×10−4)×NA×2=2×10−4NA
Step 3: Match List-I with List-II and identify the correct option○ Expand

Based on the calculations, the matches are: A-III, B-IV, C-II, D-I. Comparing this with the given options, Option 3 is the correct match.

A. 3×10−4NA→ IIIB. 7×10−4NA→ IVC. 1.5×10−4NA→ IID. 2×10−4NA→ I
💡 Teacher's Secret Hint

Double-check unit conversions (mg to g) and the count of atoms in each molecule/formula unit.

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