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Chemistry Question 74 – JEE-MAIN 2025

The amount of calcium oxide produced on heating 150 kg limestone (75% pure) is _______ kg. (Nearest integer) Given: Molar mass (in g mol1) of Ca40, O16, C12

Identify the balanced chemical equation for the thermal decomposition of limestone.

Step 1: Write the balanced chemical equation and calculate molar masses✦ Active

Limestone is primarily calcium carbonate (CaCO3). Its thermal decomposition yields calcium oxide (CaO) and carbon dioxide (CO2). The balanced chemical equation is:

CaCO3(s)CaO(s)+CO2(g)

Given molar masses: Ca=40, O=16, C=12.

Molar mass of CaCO3=40+12+(3×16)=40+12+48=100 g/mol.

Molar mass of CaO=40+16=56 g/mol.

Step 2: Calculate the mass of pure calcium carbonate○ Expand

The total mass of limestone is 150 kg, and it is 75% pure. The actual mass of pure CaCO3 available for decomposition is:

Mass of pure CaCO3=150 kg×75100=112.5 kg
Step 3: Calculate the mass of calcium oxide produced○ Expand

From the balanced equation, 1 mole of CaCO3 produces 1 mole of CaO. This means 100 g of CaCO3 produces 56 g of CaO. We can use a stoichiometric ratio to find the mass of CaO produced from 112.5 kg of CaCO3:

Mass of CaO=Mass of pure CaCO3×Molar mass of CaOMolar mass of CaCO3
Mass of CaO=112.5 kg×56 g/mol100 g/mol=112.5×0.56=63 kg

The amount of calcium oxide produced is 63 kg. The nearest integer is 63.

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