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Chemistry Question 126 – AP-EAMCET 2026

An ideal gas is cooled from 400 K to 324 K. What is the decrease in urms of the gas?

The root mean square (RMS) velocity of gas molecules is directly related to the absolute temperature of the gas. Understanding this relationship is key to solving the problem.

Step 1: Establish the relationship between urms and temperature✦ Active

The root mean square velocity (urms) of an ideal gas is directly proportional to the square root of its absolute temperature (T). This relationship is given by the formula:

urmsT

Therefore, the ratio of urms at two different temperatures T1 and T2 can be written as:

urms,2urms,1=T2T1
💡 Teacher's Secret Hint

Remember that temperature must always be in Kelvin (absolute temperature) when using gas laws and kinetic theory formulas. The problem provides temperatures in Kelvin, so no conversion is needed.

Step 2: Calculate the ratio of final to initial urms○ Expand

Given initial temperature T1=400 K and final temperature T2=324 K. Substitute these values into the ratio formula:

urms,2urms,1=324 K400 K

Simplify the square root:

urms,2urms,1=182202=1820=910=0.9

This means the final urms is 0.9 times the initial urms, or urms,2=0.9urms,1.

💡 Teacher's Secret Hint

Simplifying fractions under the square root before taking the root can sometimes make calculations easier. Recognize perfect squares like 324=182 and 400=202.

Step 3: Calculate the percentage decrease in urms○ Expand

The decrease in urms is the initial value minus the final value:

Decrease=urms,1urms,2

Substitute urms,2=0.9urms,1:

Decrease=urms,10.9urms,1=0.1urms,1

To express this as a percentage decrease, divide by the initial value and multiply by 100%:

Percentage Decrease=Decreaseurms,1×100%
Percentage Decrease=0.1urms,1urms,1×100%=0.1×100%=10%
💡 Teacher's Secret Hint

Always ensure you divide by the initial value when calculating percentage decrease or increase. A common mistake is to divide by the final value.

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