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Chemistry Question 63 – NEET-UG 2023

The relation between nm, (nm = the number of permissible values of magnetic quantum number (m)) for a given value of azimuthal quantum number (l), is

Recall the definitions and allowed values for azimuthal and magnetic quantum numbers.

🥷
Ninja StrategyTest with Simple Values

By testing the simplest case (l=0), options (2) and (4) can be quickly eliminated, narrowing down the choices to (1) and (3).

Step 1: Recall the relationship between l and m✦ Active

For a given azimuthal quantum number (l), the magnetic quantum number (m) can take integer values from l to +l, including 0. These values are: l,(l1),,1,0,1,,(l1),l.

Step 2: Calculate the number of permissible values of m○ Expand

The total number of permissible values of m, denoted as nm, is given by the formula:

nm=(l)(l)+1=l+l+1=2l+1
💡 Teacher's Secret Hint

Remember that the count includes zero and both positive and negative integers.

Step 3: Match with the given options○ Expand

We have the relation nm=2l+1. Let's rearrange this to match the options:

nm1=2l
l=nm12

This matches option (1).

💡 Teacher's Secret Hint

Always check if the derived formula can be rearranged to match one of the options.

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